Electron-transfer activation. Photocyanation of tertiary amines.

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Abstract

An efficient photoinduced cyanation of various alkaloids by Me3SiCN in acetonitrile, sensitized by N,N'-dimethyl-2,7-diazapyrenium-bis-(tetrafiuoroborate) (DAP2+, 2 BF4-), is described. © 1990.

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Santamaria, J., Kaddachi, M. T., & Rigaudy, J. (1990). Electron-transfer activation. Photocyanation of tertiary amines. Tetrahedron Letters, 31(33), 4735–4738. https://doi.org/10.1016/S0040-4039(00)97719-0

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