Preparation of mg(Oh)2 /calcined fly ash nanocomposite for removal of heavy metals from aqueous acidic solutions

Abstract

A magnesium hydroxide (MH)-modified calcined fly ash (CFA) nanocomposite (CFAMH) with core-shell structure was obtained with a heterogeneous nucleation method, and its application for removal of copper, zinc and nickel ions from aqueous acidic solution was studied. The microstructure and surface properties of CFA, CFAMH and MH powders were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller specific surface area (BET), X-ray diffraction (XRD) and Fourier translation infrared spectroscopy (FTIR), respectively. The preparation mechanism of CFAMH was discussed based on zeta potential and FTIR data. The results showed that nano-flake MH with thickness 13.4 nm was well coated on the surface of CFA. The specific surface area was increased from 2.5 to 31.0 m2 /g. Si-O-Mg-OH bonds formed from the condensation of Si-OH and Mg-OH. The removal efficiency of heavy metals on CFAMH nanocomposite is higher than that of CFA and MH and follows an order of Cu2+ > Zn2+ > Ni2+ . Solubility product constant (Ksp) is an important constant for the removal order of heavy metals on FA, CFAMH and MH. CFAMH nanocomposite can be a cheap material for removing heavy metal ions from acidic wastewater.