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Highly diastereoselective titanium(II)-mediated cyclizations of 1,7-(silyloxy)enynes

Arkivoc (2008) 2008(16) 110-118
DOI: 10.3998/ark.5550190.0009.g11
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Abstract

Cyclization of 1,7-(silyloxy)enynes with Ti(i-PrO)4 and n-BuLi yields 6-membered cyclic siloxanes in moderate to good yields. The reaction is highly diastereoselective (typical d.r.'s >15:1). © ARKAT USA, Inc.

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Barbour, N. M., & Phillips, A. J. (2008). Highly diastereoselective titanium(II)-mediated cyclizations of 1,7-(silyloxy)enynes. Arkivoc, 2008(16), 110–118. https://doi.org/10.3998/ark.5550190.0009.g11

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