Effect of MDP-Based Silane and Different Surface Conditioner Methods on Bonding of Resin Cements to Zirconium Framework

Abstract

Purpose: To determine the shear bond strength (SBS) between zirconium framework and resin cements after different surface conditioner methods and after application of 10-methacryloyloxydecyl dihydrogen phosphate (MDP) based silane and a bonding agent mix. Materials and Methods: 128 disc-shaped zirconium-oxide specimens were prepared. Specimens were placed in autopolymerizing acrylic resin. The bonding surface of specimens was smoothed consecutively with 600-, 800-, and 1200-grit silicon carbide papers under water cooling. Eight groups were prepared: CJ, Co-Jet; N, Nd-YAG laser; E, Er-YAG laser; NS, Nd-YAG laser + silane; ES, Er-YAG laser + silane; CJB, Co-Jet + bonding agent; NSB, Nd-YAG laser + silane + bonding agent; ESB, Er-YAG laser + silane + bonding agent. SEM analysis was performed under 2000× magnification. Dual- and self-cured resin cements were bonded to specimens, and shear force was applied. Data were analyzed with one-way ANOVA and Tukey's multiple comparison test (p < 0.05). Results: The SBS values differed from each other among the groups. While the CJB group showed the highest values, the N group showed the lowest. The treatment with MDP-based silane and bonding agent mix increased SBS values of each cement belonging to each group. SB values of dual-cure resin cement were higher than those of self-cure resin cements. Conclusion: Different surface conditioner methods exhibit an important effect on the SBS of resin cements to zirconium. The application of MDP-based silane and bonding agent mix enhanced SB values.