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Polymerization of styrene with cyclopentadienyl nickel complex/methylaluminoxane

IOP Conference Series: Materials Science and Engineering (2017) 231(1)
DOI: 10.1088/1757-899X/231/1/012135
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Abstract

Polystyrene was synthesized by Cp(CH2CH2OCH3)NiCl(PPh3) in the presence of methylaluminoxane (MAO). This complex displayed a very high activity for styrene polymerization up to 107 g.mol-1Nih-1. 76.6% styrene was converted to polystyrene (PS) with an average molecular (Mn) of 1.13×105 at 50 °C in 30 min. The structure of the obtained polymer was characterized by 1H NMR and FT-IR.

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Yu, D., & Zhang, D. (2017). Polymerization of styrene with cyclopentadienyl nickel complex/methylaluminoxane. In IOP Conference Series: Materials Science and Engineering (Vol. 231). Institute of Physics Publishing. https://doi.org/10.1088/1757-899X/231/1/012135

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