Thermal-mechanical properties of polyurethane-clay shape memory polymer nanocomposites

Abstract

Shape memory nanocomposites of polyurethane (PU)-clay were fabricated by melt mixing of PU and nano-clay. Based on nano-indentation and microhardness tests, the strength of the nanocomposites increased dramatically as a function of clay content, which is attributed to the enhanced nanoclay-polymer interactions. Thermal mechanical experiments demonstrated good mechanical and shape memory effects of the nanocomposites. Full shape memory recovery was displayed by both the pure PU and PU-clay nanocomposites. © 2010 by the authors.