Abstract
The flip side: Both the charged and uncharged products formed by C-H bond electrophilic activation have been experimentally detected in the gas phase. The HOinf2/infsup./sup radical is formed by a process involving the prototypical oxygen-centered radical cation Oinf2/infsup.+/sup and the methane derivative CHinf2/infFinf2/inf. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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De Petris, G., Angelini, G., Ursini, O., Rosi, M., & Troiani, A. (2012). Linking ion and neutral chemistry in C-H bond electrophilic activation: Generation and detection of HOinf2/infsup./sup reactive radicals in the gas phase. Angewandte Chemie - International Edition, 51(6), 1455–1458. https://doi.org/10.1002/anie.201107224
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