Cold Collisions in a Molecular Synchrotron

Abstract

We study collisions between neutral, deuterated ammonia molecules (ND3) stored in a 50 cm diameter synchrotron and argon atoms in copropagating supersonic beams. The advantages of using a synchrotron in collision studies are twofold: (i) By storing ammonia molecules many round-Trips, the sensitivity to collisions is greatly enhanced; (ii) the collision partners move in the same direction as the stored molecules, resulting in low collision energies. We tune the collision energy in three different ways: by varying the velocity of the stored ammonia packets, by varying the temperature of the pulsed valve that releases the argon atoms, and by varying the timing between the supersonic argon beam and the stored ammonia packets. These give consistent results. We determine the relative, total, integrated cross section for ND3+Ar collisions in the energy range of 40-140 cm-1, with a resolution of 5-10 cm-1 and an uncertainty of 7%-15%. Our measurements are in good agreement with theoretical scattering calculations.