Design, Fabrication and Characterization of Pressure-Responsive Films Based on the Orientation Dependence of Plasmonic Properties of Ag@Au Nanoplates

Abstract

A novel pressure-responsive polymer composite film was developed based on Ag@Au composite nanoplates (NPLs) and polyvinylpyrrolidone (PVP) by using Au nanoparticles as concentration reference. The orientation change of Ag@Au NPLs is impelled by the deformation of polymer matrix under pressure, resulting in its localized surface plasmon resonance (LSPR) intensity change of in-plane dipolar peak. The intensity ratio between plasmon peak of Au nanoparticles and in-plane dipolar peak of Ag@Au NPLs relies on the intensity and duration of pressure. By adjusting the viscosity of the polymer, the orientation change of LSPR may respond to a wide range of stresses. This pressure sensitive film can be utilized to record the magnitude and distribution of pressure between two contacting surfaces via optical information.