Photocatalytic degradation of organic pollutants using Trianthema Portulastrum leaf extract based CeO2 nanoparticles

Abstract

Comparison of bio CeO2-Nps prepared using Trianthema Portulastrum leaf extract with chemical CeO2-Nps is of interest. The ultraviolet - visible, x-ray diffraction, HR - TEM, FT - IR, and photoluminescence studies were conducted with CeO2-Nps. UV–Maximum absorptionat 292 nm was completed using UV-visible spectrum. The HR–TEM images showed 38 nm bio CeO2-Nps with spherical morphology. This showed the polycrystalline character of CeO2-Nps similar to XRD data. The presence of metal oxide is confirmed by FT - IR analyses. The CeO2-Nps showed the potential photocatalytic activity for Acid black 1 color degradation after exposure to sunlight. Chem and bio CeO2-Nps have a degradation rate of 86.66 and 94.33%, respectively for acid black 1 dye. The synthesized CeO2-Nps are also evaluated for antibacterial and antioxidant activity. The bio CeO2-Nps has antibacterial activity for Pseudomonas aeruginosa (17 ± 0.56 mm) and Staphylococcus aureus (16 ± 0.24 mm) at low concentrations of 100 μl. The CeO2-Nps bio showed high inhibition of radical DPPH IC50 μg/ml, at 95.17 ± 21. Thus, we show that CeO2-Nps have environmentally friendly properties that are useful for dye degradation with antimicrobial and antioxidant activities.